• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A process for forming polymeric polyamine/amide wherein said amino/amido nitrogens are positioned in the polymer backbone by contacting a monomeric nitrogen compound which has at least two labile hydrogens bonded to the nitrogen atoms therein; a monomeric hydrocarbon compound containing at least two olefinic groups therein; carbon monoxide; and water in the presence of a catalytic amount of a rhodium atom containing compound selected from metallic rhodium, rhodium salts, rhodium oxides, rhodium carbonyls and ligands thereof at a temperature of from about 50 DEG C. to 250 DEG C. and at a pressure of from about 30 to about 300 atmospheres.
    公开号:SU1197567A3
    申请号:SU813248460
    申请日:1981-02-20
    公开日:1985-12-07
    发明作者:Ячимович Фелек
    申请人:В.Р.Грейс Энд Ко (Фирма)；
    IPC主号:
    专利说明:

    with
    SP
    a The invention relates to catalytic one-step processes for the preparation of polymeric materials containing amino groups. The purpose of the invention is to simplify the process of obtaining polymers. Example 1. A 150 ml stainless steel vessel is loaded with 4 g of piperazine, 0.8 ml of water, 10 ml of s-1 ml of niperidine, 5 ml of 1.5-g of sadiena and 120 mg of tris (dimethylphenylphosphine) norbornadiene-born {Rh (hexafluorophosphate) NBD) (cH,) pCCgHg) PF; i The ratio of equivalent number of olefin and amino groups 1: 1, water and amino groups 1: 1, carbon monoxide and water 10: 1. The reaction vessel is isolated and carbon monoxide is injected into the vessel to a pressure of 1000 psi. The isolated vessel is placed in a knot oil bath and left for 8 ti o. o at 140 C. About 3.5 g of a red-brown precipitate are obtained. The precipitate is dissolved in tetrahydrofuran and precipitated out with water. Solids are analyzed by proton NMR on the content of tertiary amino groups in it. It is then dissolved in an aqueous solution of HC1 (pH 1.5), which indicates the presence of an amine structure. Example 2. A stainless steel vessel was charged with 20 ml of N-methyl pyrrolidine, 1.8 ml of deionized water, 3.3 ml of ethylenediamine (2: 1 ratio of olefinic and amino groups, 2: 1 of water and amino groups, and water 6: 1), 4 mg of hydroquinone hexafluorophosphate 1,2-bis (diphenylphosphine) ethannorbornadiene rhodi. The volume of the vessel 150 ml. Then 3 ml of 1,3-butadiene is loaded into the vessel and carbon monoxide is pumped at 40 ° C to a pressure of 10,000 psi. The reactor is then placed in a gauze bath knot and held for 10 hours at HOt. The reactor is cooled and a reddish-brown, sticky solid is obtained, which is soluble in various organic solvents and aqueous HC1 (pH 1.5). Example 3. The procedures of experiments 2 and 3 are repeated except that in each experiment the catalyst is replaced by / Rh / CO / / C R4 / CO / ,,; RhCl, / C, H, N;, H-fRhCl, / C, He (| In each case, a solid product is obtained, similar to the products obtained in Examples 1 and 2. Example 4: The experiment is carried out as in 1, with the exception of ToVo, N-methylpiperidine, take tert-butanol in an equivalent amount. A product similar to that obtained in Example 1 is obtained. Example 5. The reaction is carried out under the conditions and using the reagents described in Example 1. The difference is that the closed reactor was placed in a shaking oil bath for 8 hours at. A similar reaction was carried out at 200 ° C. The product in both cases is identical to the product obtained in Example 1.
    权利要求:
    Claims (3)
    [1]
    1. METHOD FOR PRODUCING POLYAMINAMIDE CONTAINING AMINAMIDE GROUPS IN THE BASIC CHAIN OF THE MACROMOLECULE by polymerization of an amine in the presence of a solvent, characterized in that, in order to simplify the process, an amine containing 2-4 active hydrogen atoms is introduced into the reaction mixture 1,5-hexadiene or 1,3-butadiene, water and carbon monoxide to a ratio of equivalent amounts of olefinic and amino groups 1: 1-2: 1, water and amino groups 1: 1-2: 1, carbon monoxide and water 10: 1- 6: 1, the reaction mixture is heated to 100-200 C and polymerization is carried out vlyayut at 40-95 atm in the presence of a catalyst selected from the group consisting of salts, carbonyls and rhodium complex compounds, which are soluble in the reaction medium.
    [2]
    2. The method according to n, characterized in that it is carried out at a molar ratio of the number of rhodium atoms contained in the catalyst to the number of double bonds equal to 1 · 10 ~ 4 - 2.5 10 ' 3 .
    1197567 1 carbon monoxide and water 6: 1), 4 mg hydroquinone hexafluorophosphate 1,2-bis (diphenylphosphine) ethannorbornadiene rhodium. The volume of the vessel is 150 ml. Then in
    [3]
    5 vessel was charged with 3 MP and 1,3-butadiene is injected at 40 C d of carbon monoxide to a pressure of 1000 lbs / in2. Then the reactor is placed in an oil banjat and incubated for 10 hours at 140 ° C. The reactor is cooled and a reddish-brown sticky solid product is obtained, which is soluble in various organic solvents and aqueous HC1 (pH 1.5).
    Example 3. The procedures of experiments 2 and 3 are repeated except that the catalyst in each of the experiments is replaced by / Rh / C0 / 2 / H 7 0 2 /;
    Rh 6 / C0 / | 6 ; RhCl, (C 5 H 5 K), and fRhCl, (C, 1C. In each case, a solid product is obtained, similar to the products obtained in ^ examples 1 and 2.
    Example 4. The experience is carried out
    25 according to Example 1, except that instead of N-methylpiperidine, tert-butanol is taken in an equivalent amount. Get a product similar to the product obtained in example 1.
    30 Example 5. The reaction is carried out under the conditions and using the reagents described in example 1. The difference is that the closed reactor is placed in a shaken 35 oil bath for 8 hours at 100 ° C. A similar reaction is carried out at 200 ° C. The resulting product in both cases is identical to the product obtained in example 1.
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    SU1197567A3|1985-12-07|Method of producing polyaminamide containing aminamide groups in basic chain of macromolecule
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    同族专利:
    公开号 | 公开日
    FI67872C|1985-06-10|
    BE887627A|1981-06-15|
    DE3106139C2|1990-01-11|
    ES499654A0|1982-02-01|
    IT8026424D0|1980-12-03|
    GB2073218B|1984-06-27|
    FI67872B|1985-02-28|
    DE3106139A1|1981-12-17|
    IT1193998B|1988-08-31|
    GB2073218A|1981-10-14|
    FI804062L|1981-08-23|
    NL186092C|1990-09-17|
    FR2476659B1|1985-07-12|
    NL8006674A|1981-09-16|
    SE8009108L|1981-08-23|
    FR2476659A1|1981-08-28|
    ES8202843A1|1982-02-01|
    NL186092B|1990-04-17|
    SE444442B|1986-04-14|
    US4297481A|1981-10-27|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US2422631A|1944-11-07|1947-06-17|Sharples Chemicals Inc|Manufacture of aliphatic amines and acid amides|
    US3513200A|1968-11-25|1970-05-19|Union Oil Co|Preparation of tertiary amines|
    US3899534A|1971-10-12|1975-08-12|California Inst Of Techn|Cross-linked polyelectrolytes|
    US3898188A|1972-08-14|1975-08-05|California Inst Of Techn|Novel polyelectrolytes|
    FR2211002A5|1972-12-20|1974-07-12|Rhone Progil|US5191101A|1982-11-22|1993-03-02|Minnesota Mining And Manufacturing Company|Energy polymerizable compositions containing organometallic initiators|
    US4866177A|1986-11-24|1989-09-12|Texaco Inc.|Process for one-step synthesis of amides|
    US4940775A|1988-07-13|1990-07-10|Shell Oil Company|Polyketone from carbon monoxide/monoethylenically unsaturated hydrocarbon/non-conjugated alkadiene|
    GB2226821A|1988-12-29|1990-07-11|Shell Int Research|Process for the carbonylation polymerization of dienes in the presence of dicarboxylic acids or diols as coreactants|
    CA2086527A1|1990-07-26|1992-01-27|Samuel J. Tremont|Polymeric drug delivery system|
    MX9307894A|1992-12-14|1994-06-30|Monsanto Co|CONTROLLED POLYIN ITS FUNCTIONAL DENSITY, AND METHOD FOR ITS PREPARATION.|
    US5559193A|1993-12-20|1996-09-24|Monsanto Company|Controlled functional density polyamines and method for preparation thereof|
    US5773567A|1996-06-17|1998-06-30|Exxon Chemical Patents Inc|Carboxylic amide-containing polymers for use as fuel or lubricating oil additives and processes for their preparation|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    US06/123,739|US4297481A|1980-02-22|1980-02-22|Process of forming polymeric polyamine/amide|
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